Hi all - interesting topic. Below is some information from Wikipedia on these extinguishers.
In 1910, The Pyrene Manufacturing Company of Delaware filed a patent for an extinguisher using carbon tetrachloride (CTC) to extinguish fires. The CTC vaporized and extinguished the flames by creating a dense, oxygen-excluding blanket of fumes, and to a lesser extent, inhibiting the chemical reaction. In 1911, they patented a small, portable extinguisher that used the chemical. This consisted of a brass or chrome container with an integrated handpump, which was used to expel a jet of liquid towards the fire. It was usually of 1 imperial quart (1.1 L) or 1 imperial pint (0.6 L) capacity but was also available in up to 2 imperial gallon (9 L) size. As the container was unpressurized, it could be refilled after use through a filling plug with a fresh supply of CTC.
Another type of carbon-tetrachloride extinguisher was the Fire grenade. This consisted of a glass sphere filled with CTC, that was intended to be hurled at the base of a fire (early ones used salt-water, but CTC was more effective). Carbon tetrachloride was suitable for liquid and electrical fires and the extinguishers were fitted to motor vehicles. Carbon-tetrachloride extinguishers were withdrawn in the 1950s because of the chemical's toxicity–exposure to high concentrations damages the nervous system and internal organs. Additionally, when used on a fire, the heat can convert CTC to Phosgene gas, formerly used as a chemical weapon.
Bob